Evolution of phosphorus-vacancy clusters in epitaxial germanium

Anurag Vohra, Afrina Khanam, Jonatan Slotte, Ilja Makkonen, Geoffrey Pourtois, Roger Loo, Wilfried Vandervorst

Research output: Contribution to journalArticleScientificpeer-review

6 Citations (Scopus)
37 Downloads (Pure)

Abstract

The E centers (dopant-vacancy pairs) play a significant role in dopant deactivation in semiconductors. In order to gain insight into dopant-defect interactions during epitaxial growth of in situ phosphorus doped Ge, positron annihilation spectroscopy, which is sensitive to open-volume defects, was performed on Ge layers grown by chemical vapor deposition with different concentrations of phosphorus (∼ 1 × 10 18- 1 × 10 20 cm - 3). Experimental results supported by first-principles calculations based on the two component density-functional theory gave evidence for the existence of mono-vacancies decorated by several phosphorus atoms as the dominant defect type in the epitaxial Ge. The concentration of vacancies increases with the amount of P-doping. The number of P atoms around the vacancy also increases, depending on the P concentration. The evolution of P n-V clusters in Ge contributes significantly to the dopant deactivation.

Original languageEnglish
Article number025701
JournalJournal of Applied Physics
Volume125
Issue number2
DOIs
Publication statusPublished - 14 Jan 2019
MoE publication typeA1 Journal article-refereed

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  • Projects

    Large-scale electronic structure techniques for advanced materials characterization

    Simula, K. & Makkonen, I.

    01/09/201808/11/2019

    Project: Academy of Finland: Other research funding

    Large-scale electronic structure techniques for advanced materials characterization

    Makkonen, I.

    01/09/201522/09/2019

    Project: Academy of Finland: Other research funding

    Large-scale electronic structure techniques for advanced materials characterization

    Makkonen, I., Simula, K., Prozheeva, V. & Härkönen, J.

    01/09/201521/09/2018

    Project: Academy of Finland: Other research funding

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