Evolution of nanostructured single-phase CoSb3 thin films by low-energy ion beam induced mixing and their thermoelectric performance

Manju Bala, Srashti Gupta, Sanjeev K. Srivastava, Sankarakumar Amrithapandian, Tripurari S. Tripathi, Surya K. Tripathi, Chung-Li Dong, Chi-Liang Chen, Devesh K. Avasthi, Kandasami Asokan*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

8 Citations (Scopus)

Abstract

Skutterudites are emerging as potential candidates that show high efficiency and thus provide an ideal platform for research. The properties of nanostructured films of skutterudites are different from those of the corresponding bulk. The present study reports the evolution of nanostructured single-phase CoSb3 fabricated by using low-energy ion irradiation of Co/Sb bilayer films and subsequent annealing at an optimized temperature and their Seebeck coefficients (S). The effects of ion beam parameters with annealing on the phase evolution and nanostructure modifications were studied. An increase in Xe+ ion fluence resulted in complete mixing of Co/Sb on postannealing forming flower-like nanostructures of single phase CoSb3. The temperature-dependent electrical resistivity (ρ) increases with the ion fluence because of defect creation which further increases on postannealing due to surface nanostructuring. The S of these films of CoSb3 is found to be higher and this is attributed to the formation of a uniform layer of nanostructured CoSb3 alloy thin film. The S and Hall coefficients of all these films are negative implying that they are n-type semiconductors.

Original languageEnglish
Pages (from-to)24886-24895
Number of pages10
JournalPhysical Chemistry Chemical Physics
Volume19
Issue number36
DOIs
Publication statusPublished - 2017
MoE publication typeA1 Journal article-refereed

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    Bala, M., Gupta, S., Srivastava, S. K., Amrithapandian, S., Tripathi, T. S., Tripathi, S. K., Dong, C-L., Chen, C-L., Avasthi, D. K., & Asokan, K. (2017). Evolution of nanostructured single-phase CoSb3 thin films by low-energy ion beam induced mixing and their thermoelectric performance. Physical Chemistry Chemical Physics, 19(36), 24886-24895. https://doi.org/10.1039/c7cp03527f