Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios

J. V. Seppälä

doi:10.1021/ma00154a012

Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios

J. V. Seppälä^*

^*Corresponding author for this work

Not published at Aalto University

Research output: Contribution to journal › Article › Scientific › peer-review

9 Citations (Scopus)

Abstract

The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C₁₀, C₁₂, and C₁₆ α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by ¹³C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.

Original language	English
Pages (from-to)	2409-2412
Number of pages	4
Journal	Macromolecules
Volume	18
Issue number	12
DOIs	https://doi.org/10.1021/ma00154a012
Publication status	Published - 1985
MoE publication type	A1 Journal article-refereed

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title = "Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios",

abstract = "The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C10, C12, and C16 α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by 13C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.",

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year = "1985",

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AU - Seppälä, J. V.

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N2 - The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C10, C12, and C16 α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by 13C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.

AB - The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C10, C12, and C16 α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by 13C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.

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