Engineering of a highly stable metal-organic Co-film for efficient electrocatalytic water oxidation in acidic media

Hussein A. Younus, M. Vandichel, Nazir Ahmad, Elisabet Ahlberg, Michael Busch, Francis Verpoort*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

2 Citations (Scopus)

Abstract

Water oxidation is traditionally performed over IrO2 and RuO2 owing to their high stability at low pH compared to molecular O2 evolution catalysts. The low stability of molecular complexes in acids limits their industrial exploitation as anodes in water-splitting devices, where high current densities and proton conductivity are required. Herein, an existing Co(1,10-phenanthroline)2 complex film is engineered to improve its pH-stability via extra OH substituents on the ligand, i.e. 1,10-phenanthroline-4,7-diol. This novel Co(1,10-phenanthroline-4,7-diol)2 complex film is active for water oxidation at low overpotentials and stable at low pH. Since the calculated water oxidation overpotentials of both complexes are similar, the difference in water oxidation activity is attributed to a smaller charge transfer resistance, which originates from a different anchoring style to the electrode via the OH groups of the ligand. This result is supported by electrochemical impedance measurements. The high pH-stability of the Co(1,10-phenanthroline-4,7-diol)2 film is computationally rationalized by a high crystal formation energy observed in DFT calculations. In summary, an acid-stable and active cobalt-based metal-organic film is reported that competes well with most reported earth-abundant catalysts for water oxidation under similar conditions.

Original languageEnglish
Article number100437
JournalMaterials Today Energy
Volume17
DOIs
Publication statusPublished - Sep 2020
MoE publication typeA1 Journal article-refereed

Keywords

  • DFT
  • Electrocatalysts
  • Molecular catalysts
  • Organometallic film
  • Oxygen evolution reaction (OER)
  • Water splitting

Fingerprint Dive into the research topics of 'Engineering of a highly stable metal-organic Co-film for efficient electrocatalytic water oxidation in acidic media'. Together they form a unique fingerprint.

  • Cite this