Early stage oxidation behavior of Al- and Si-alloyed stainless steels as well as Ni-based alloys in air at elevated temperatures

Jyrki Romu, Teemu Sarikka, Mikko Heikkilä, Iikka Virkkunen, Hannu Hänninen

Research output: Contribution to journalArticleScientificpeer-review

6 Citations (Scopus)

Abstract

Several alloys including Al-alloyed austenitic and ferritic stainless steels, Ni-based alloy and Si-alloyed ferritic stainless steel were annealed at 550, 750, and 950 °C for up to 700 h. AISI 347HFG and 10CrMo910 were used as reference materials. Weight gain was measured and the samples were analyzed with SEM/EDS and XRD. Materials having high enough Al-content performed best due to ability to form a continuous protective Al2O3-oxide layer on their surface at elevated temperatures. Lower Al-content materials were not able to form a continuous protective Al-oxide on their surface and suffered from accelerated internal Al-oxide formation due to alloying elements. Si-alloying improves the oxidation resistance of the studied materials and their performance was practically in the same level as that of the best Al-alloyed materials. In Al-alloyed materials the crystallinity of Al2O3 on ferritic stainless steel weld metal was higher than that on welded and wrought austenitic stainless steels.

Original languageEnglish
Pages (from-to)690-702
Number of pages13
JournalMaterials and Corrosion
Volume69
Issue number6
Early online date3 Jan 2018
DOIs
Publication statusPublished - 1 Jun 2018
MoE publication typeA1 Journal article-refereed

Funding

Finnish Funding Agency for Technology and Innovation (Tekes) The work was carried out within the Digital, Internet, Materials, and Engineering Co-Creation (DIMECC) and its Breakthrough Steels and Applications (BSA) program. We gratefully acknowledge the financial support from the Finnish Funding Agency for Technology and Innovation (Tekes). We also want to thank the Oak Ridge National Laboratory and the Carpenter Technology Corporation for providing the AFA alloys and the Massachusetts Institute of Technology for providing the 12Cr2SiFe alloy for the study.

Keywords

  • Al-alloyed
  • crystal structure
  • Ni-base alloy
  • oxidation
  • Si-alloyed
  • stainless steel

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