Development of novel methods for production of cellulose-based materials

Pegah Khanjani

Research output: ThesisDoctoral ThesisCollection of Articles

Abstract

Modern technology requires sustainable solutions for future new applica-tions. Different types of cellulose such as cellulose nanocrystals (CNCs) and microfibrillated cellulose (MFC) are of particular interest as renewable, highly functionalizable and widely available raw materials. In this thesis, various novel methods for the production of cellulose-based materials were explored. The main findings of this study can be divided into two parts: (i) introducing a method for assessing the reactivity of cellu-lose in chemical pulps and bacterial cellulose (BC) under mild conditions (RT and pH 9) (Paper I) and ii) investgating several approaches for the chemical functionalization of cellulose as an easy way to adjust the properties of the macromolecule for various purposes. Esterification of cellu-lose with long-chain aliphatic acid chloride is an effective technique for enhancing the hydrophobicity of cellulose, which can then be used as a coating (Paper II). Another crucial route of cellular functionalization is TEMPO-mediated ox-idation, which forms carboxyl groups on the surface of MFC. Crosslinking of these carboxyl groups with metal ions under specific conditions leads to increased tensile strength of the cellulosic film (Paper III and IV). The results yield different approaches to the cellulose reactivity and to improve the water-resistance and tensile strength of the paper and Films, respectively, which may create many renewable options in various applications to replace fossil raw materials.
Translated title of the contributionDevelopment of novel methods for production of cellulose-based materials
Original languageEnglish
QualificationDoctor's degree
Awarding Institution
  • Aalto University
Supervisors/Advisors
  • Vuorinen, Tapani, Supervising Professor
  • Vuorinen, Tapani, Thesis Advisor
Publisher
Print ISBNs978-952-60-8510-4
Electronic ISBNs978-952-60-8511-1
Publication statusPublished - 2019
MoE publication typeG5 Doctoral dissertation (article)

Keywords

  • cellulose nanocrystals
  • microfibrillated cellulose
  • pulp
  • reactivity
  • TEMPO-mediated oxidation
  • esterification
  • film

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