Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report)

S. Beuermann; M. Buback; T. Davis; R. Hutchinson; B. Klumperman; A. Kajuewara; I. Lacik; G. Russell; A. Abe; I. Ando; M. Baron; D. Berek; H. Chan; J. Y F Chen; G. Costa; J. Economyu; G. Fuller; R.G. Gilbert; M. Hess; S. Hvilsted; K. Horic; J-I. Jin; R. Jones; A.R. Khokhlov; P. Kratochvil; P. Kubisa; H.M. Laun; J-P. Pascault; S. Penczek; J.M. Perena; E. Reichmanis; R.D. Sanderson; J.V. Seppälä; A. Gomes; Tabak de Souza; H. Tenhu; J-P. Vairon; J. Vohlidal; F. Wang; W.J. Work

Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report)

S. Beuermann, M. Buback, T. Davis, R. Hutchinson, B. Klumperman, A. Kajuewara, I. Lacik, G. Russell, A. Abe, I. Ando, M. Baron, D. Berek, H. Chan, J. Y F Chen, G. Costa, J. Economyu, G. Fuller, R.G. Gilbert, M. Hess, S. HvilstedK. Horic, J-I. Jin, R. Jones, A.R. Khokhlov, P. Kratochvil, P. Kubisa, H.M. Laun, J-P. Pascault, S. Penczek, J.M. Perena, E. Reichmanis, R.D. Sanderson, J.V. Seppälä, A. Gomes, Tabak de Souza, H. Tenhu, J-P. Vairon, J. Vohlidal, F. Wang, W.J. Work

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

Propagation rate coefficients, kp, as a function of temperature, are reported
for bulk free-radical homopolymerizations of oxiranylmethyl, cyclohexyl,
and benzyl methacrylate at ambient pressure and low conversion. The data were
obtained from experiments combining pulsed-laser initiated polymerization and
size-exclusion chromatography. The data determined from experiments carried out
in independent laboratories obey the consistency criteria established for this technique. The rate coefficients for the three monomers are well represented by a single Arrhenius relation.

Original language	English
Pages (from-to)	1091-1096
Journal	Pure and Applied Chemistry
Volume	75
Issue number	8
Publication status	Published - 2003
MoE publication type	A1 Journal article-refereed

Keywords

cyclic ester groups
free-radical polymerization

Cite this

Beuermann, S., Buback, M., Davis, T., Hutchinson, R., Klumperman, B., Kajuewara, A., Lacik, I., Russell, G., Abe, A., Ando, I., Baron, M., Berek, D., Chan, H., Chen, J. Y. F., Costa, G., Economyu, J., Fuller, G., Gilbert, R. G., Hess, M., ... Work, W. J. (2003). Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report). Pure and Applied Chemistry, 75(8), 1091-1096.

@article{0fcca25b43f746f289b18685037e752c,

title = "Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report)",

abstract = "Propagation rate coefficients, kp, as a function of temperature, are reportedfor bulk free-radical homopolymerizations of oxiranylmethyl, cyclohexyl,and benzyl methacrylate at ambient pressure and low conversion. The data wereobtained from experiments combining pulsed-laser initiated polymerization andsize-exclusion chromatography. The data determined from experiments carried outin independent laboratories obey the consistency criteria established for this technique. The rate coefficients for the three monomers are well represented by a single Arrhenius relation.",

keywords = "cyclic ester groups, free-radical polymerization, cyclic ester groups, free-radical polymerization, cyclic ester groups, free-radical polymerization",

author = "S. Beuermann and M. Buback and T. Davis and R. Hutchinson and B. Klumperman and A. Kajuewara and I. Lacik and G. Russell and A. Abe and I. Ando and M. Baron and D. Berek and H. Chan and Chen, {J. Y F} and G. Costa and J. Economyu and G. Fuller and R.G. Gilbert and M. Hess and S. Hvilsted and K. Horic and J-I. Jin and R. Jones and A.R. Khokhlov and P. Kratochvil and P. Kubisa and H.M. Laun and J-P. Pascault and S. Penczek and J.M. Perena and E. Reichmanis and R.D. Sanderson and J.V. Sepp{\"a}l{\"a} and A. Gomes and {de Souza}, Tabak and H. Tenhu and J-P. Vairon and J. Vohlidal and F. Wang and W.J. Work",

year = "2003",

language = "English",

volume = "75",

pages = "1091--1096",

journal = "Pure and Applied Chemistry",

issn = "0033-4545",

publisher = "De Gruyter",

number = "8",

}

Beuermann, S, Buback, M, Davis, T, Hutchinson, R, Klumperman, B, Kajuewara, A, Lacik, I, Russell, G, Abe, A, Ando, I, Baron, M, Berek, D, Chan, H, Chen, JYF, Costa, G, Economyu, J, Fuller, G, Gilbert, RG, Hess, M, Hvilsted, S, Horic, K, Jin, J-I, Jones, R, Khokhlov, AR, Kratochvil, P, Kubisa, P, Laun, HM, Pascault, J-P, Penczek, S, Perena, JM, Reichmanis, E, Sanderson, RD, Seppälä, JV, Gomes, A, de Souza, T, Tenhu, H, Vairon, J-P, Vohlidal, J, Wang, F & Work, WJ 2003, 'Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report)', Pure and Applied Chemistry, vol. 75, no. 8, pp. 1091-1096.

TY - JOUR

T1 - Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report)

AU - Beuermann, S.

AU - Buback, M.

AU - Davis, T.

AU - Hutchinson, R.

AU - Klumperman, B.

AU - Kajuewara, A.

AU - Lacik, I.

AU - Russell, G.

AU - Abe, A.

AU - Ando, I.

AU - Baron, M.

AU - Berek, D.

AU - Chan, H.

AU - Chen, J. Y F

AU - Costa, G.

AU - Economyu, J.

AU - Fuller, G.

AU - Gilbert, R.G.

AU - Hess, M.

AU - Hvilsted, S.

AU - Horic, K.

AU - Jin, J-I.

AU - Jones, R.

AU - Khokhlov, A.R.

AU - Kratochvil, P.

AU - Kubisa, P.

AU - Laun, H.M.

AU - Pascault, J-P.

AU - Penczek, S.

AU - Perena, J.M.

AU - Reichmanis, E.

AU - Sanderson, R.D.

AU - Seppälä, J.V.

AU - Gomes, A.

AU - de Souza, Tabak

AU - Tenhu, H.

AU - Vairon, J-P.

AU - Vohlidal, J.

AU - Wang, F.

AU - Work, W.J.

PY - 2003

Y1 - 2003

N2 - Propagation rate coefficients, kp, as a function of temperature, are reportedfor bulk free-radical homopolymerizations of oxiranylmethyl, cyclohexyl,and benzyl methacrylate at ambient pressure and low conversion. The data wereobtained from experiments combining pulsed-laser initiated polymerization andsize-exclusion chromatography. The data determined from experiments carried outin independent laboratories obey the consistency criteria established for this technique. The rate coefficients for the three monomers are well represented by a single Arrhenius relation.

AB - Propagation rate coefficients, kp, as a function of temperature, are reportedfor bulk free-radical homopolymerizations of oxiranylmethyl, cyclohexyl,and benzyl methacrylate at ambient pressure and low conversion. The data wereobtained from experiments combining pulsed-laser initiated polymerization andsize-exclusion chromatography. The data determined from experiments carried outin independent laboratories obey the consistency criteria established for this technique. The rate coefficients for the three monomers are well represented by a single Arrhenius relation.

KW - cyclic ester groups

KW - free-radical polymerization

KW - cyclic ester groups

KW - free-radical polymerization

KW - cyclic ester groups

KW - free-radical polymerization

M3 - Article

SN - 0033-4545

VL - 75

SP - 1091

EP - 1096

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 8

ER -

Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. methacrylates with cyclic ester groups (IUPAC Technical Report)

Abstract

Keywords

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