COPOLYMERS OF ETHYLENE WITH BUTENE-1 AND LONG CHAIN alpha -OLEFINS. I. DECENE-1 AS LONG CHAIN alpha -OLEFIN.

Jukka Veli Seppälä*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

29 Citations (Scopus)

Abstract

The possibility was studied of using decene-1 as comonomer with ethylene in a slurry type polymerization with Ziegler-Natta catalysts. Under the reaction conditions used decene contents remained at the 2 wt% level in ethylene/decene-1 copolymers. When additionally butene-1 was present in the polymerization, decene-1 contents were significantly higher. A synergistic effect was identified in the reactivities of butene-1 and decene-1 in terpolymerization with ethylene. Decene-1 content had an effect on the polymer density and crystallinity, but virtually no effect on melting temperature.

Original languageEnglish
Pages (from-to)3545-3556
Number of pages12
JournalJournal of Applied Polymer Science
Volume30
Issue number9
DOIs
Publication statusPublished - Sept 1985
MoE publication typeA1 Journal article-refereed

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