Chemical recycling of hemp waste textiles via the ionic liquid based dry-jet-wet spinning technology

Marja Rissanen*, Inge Schlapp-Hackl, Daisuke Sawada, Susanna Raiskio, Krishna Ojha, Edward Smith, Herbert Sixta*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

7 Citations (Scopus)
104 Downloads (Pure)

Abstract

The chemical recycling of hemp fabric into high-tenacity man-made cellulose fibers was demonstrated. The fabric was laundered 25 and 50 times to mimic the wear cycles of post-consumer textile waste. Despite the launderings, the molar mass of the material was still too high for recycling via dry-jet-wet spinning. Thus, the fabrics were treated with an aqueous sulfuric acid solution to adjust the intrinsic viscosity to the targeted level of 400–500 ml/g. The acid hydrolyzed sample was dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium acetate and man-made cellulose fibers were regenerated by dry-jet-wet spinning. The properties of hemp and regenerated fibers were determined by tensile testing, birefringence measurements, and X-ray diffraction. Regenerated fibers were spun into yarn and knitted into a fabric. The tensile properties of the yarn and the abrasion and pilling resistance of the fabric were determined. Regenerated fibers showed a higher modulus of toughness (55.9 MPa) compared with hemp fibers (28.7 MPa). The fineness and staple length uniformity of regenerated fibers resulted in a high yarn structure evenness, a yarn tenacity of 28.1 cN/tex, and an elongation at break of 7.5%. Due to the even fabric structure, the fabric from regenerated fibers showed higher abrasion resistance than the hemp fabric.
Original languageEnglish
Pages (from-to)2545-2557
Number of pages13
JournalTextile Research Journal
Volume93
Issue number11-12
Early online date18 Dec 2022
DOIs
Publication statusPublished - Jun 2023
MoE publication typeA1 Journal article-refereed

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