Catalytic Activity Dependency on Catalyst Components in Aerobic Copper-TEMPO Oxidation
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amounts led to a decrease in activity for longer reaction times. The kinetic dependency for TEMPO was found to be 1.15, and for copper 2.25, which is an indication of a binuclear catalytic system. Optimised conditions with various allylic and aliphatic alcohols give good to excellent rapid oxidations.
|Journal||CHEMISTRY: A EUROPEAN JOURNAL|
|Publication status||Published - 2009|
|MoE publication type||A1 Journal article-refereed|
- alcohols, copper, homogenous catalysis, oxidation, TEMPO