Biomass-Assisted Reductive Leaching in H2SO4 Medium for the Recovery of Valuable Metals from Spent Mixed-Type Lithium-Ion Batteries

Yongming Chen; Di Chang; Nannan Liu; Fang Hu; Chao Peng; Xiaoyuan Zhou; Jing He; Yafei Jie; Henghui Wang; Benjamin P. Wilson; Mari Lundström

doi:10.1007/s11837-019-03775-3

Biomass-Assisted Reductive Leaching in H2SO4 Medium for the Recovery of Valuable Metals from Spent Mixed-Type Lithium-Ion Batteries

Yongming Chen , Di Chang, Nannan Liu, Fang Hu, Chao Peng, Xiaoyuan Zhou, Jing He, Yafei Jie, Henghui Wang, Benjamin P. Wilson, Mari Lundström

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Abstract

A hydrometallurgical method involving natural biomass waste as reductant
was proposed for the treatment of spent mixed-type lithium-ion batteries.
Results showed that almost complete dissolution of Li, Ni, Mn and nearly 90%
dissolution of Co were achieved under the optimal conditions of H2SO4 concentration of 2 M, waste tea biomass dosage of 0.3 g/g, solid/ratio of 50 g L¯¹, temperature of 90ºC and time of 120 min. The leaching kinetics was further
investigated, and the activation energies were determined to be 1.7 kJ mol¯¹,
10.3 kJ mol¯¹, 10.1 kJ mol¯¹ and 10.9 kJ mol¯¹ for Li, Ni, Mn and Co,
respectively. The cathode materials before leaching and the leaching residue
were characterized with different analytical methods. The characterization
results confirmed that the addition of the waste tea acted as reductant and
resulted in better dissolution of the metals, supporting the principles of sustainable processes by decreasing the chemical consumption and integrating
waste into a secondary use.

Original language	English
Number of pages	8
Journal	JOM
DOIs	https://doi.org/10.1007/s11837-019-03775-3
Publication status	Published - 11 Sep 2019
MoE publication type	A1 Journal article-refereed

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BATCircle (Hydro)
Lundström, M., Porvali, A., Aromaa, R., Aromaa, J., Wilson, B., Kalliomäki, T., Karppinen, A., Revitzer, H., Zhang, J., Chernyaev, A., Zou, Y., Hu, F., Ke, P., Liu, F., Rinne, M., Khalid, M. K., Palomäki, H., Partinen, J., Seisko, S., Lampinen, A., Peng, C., Sahlman, M., Wang, Z., Shukla, S., Forde, G. & Ruismäki, R.
01/01/2019 → 30/04/2021
Project: Business Finland: Other research funding

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title = "Biomass-Assisted Reductive Leaching in H2SO4 Medium for the Recovery of Valuable Metals from Spent Mixed-Type Lithium-Ion Batteries",

abstract = "A hydrometallurgical method involving natural biomass waste as reductantwas proposed for the treatment of spent mixed-type lithium-ion batteries.Results showed that almost complete dissolution of Li, Ni, Mn and nearly 90%dissolution of Co were achieved under the optimal conditions of H2SO4 concentration of 2 M, waste tea biomass dosage of 0.3 g/g, solid/ratio of 50 g L¯1, temperature of 90ºC and time of 120 min. The leaching kinetics was furtherinvestigated, and the activation energies were determined to be 1.7 kJ mol¯1,10.3 kJ mol¯1, 10.1 kJ mol¯1 and 10.9 kJ mol¯1 for Li, Ni, Mn and Co,respectively. The cathode materials before leaching and the leaching residuewere characterized with different analytical methods. The characterizationresults confirmed that the addition of the waste tea acted as reductant andresulted in better dissolution of the metals, supporting the principles of sustainable processes by decreasing the chemical consumption and integratingwaste into a secondary use.",

author = "Yongming Chen and Di Chang and Nannan Liu and Fang Hu and Chao Peng and Xiaoyuan Zhou and Jing He and Yafei Jie and Henghui Wang and Wilson, {Benjamin P.} and Mari Lundstr{\"o}m",

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AU - Chen , Yongming

AU - Chang, Di

AU - Liu, Nannan

AU - Hu, Fang

AU - Peng, Chao

AU - Zhou, Xiaoyuan

AU - He, Jing

AU - Jie, Yafei

AU - Wang, Henghui

AU - Wilson, Benjamin P.

AU - Lundström, Mari

N1 - The online version of this article (https://doi.org/10.1007/s11837-019-03775-3) contains supplementary material, which is available to authorized users.

PY - 2019/9/11

Y1 - 2019/9/11

N2 - A hydrometallurgical method involving natural biomass waste as reductantwas proposed for the treatment of spent mixed-type lithium-ion batteries.Results showed that almost complete dissolution of Li, Ni, Mn and nearly 90%dissolution of Co were achieved under the optimal conditions of H2SO4 concentration of 2 M, waste tea biomass dosage of 0.3 g/g, solid/ratio of 50 g L¯1, temperature of 90ºC and time of 120 min. The leaching kinetics was furtherinvestigated, and the activation energies were determined to be 1.7 kJ mol¯1,10.3 kJ mol¯1, 10.1 kJ mol¯1 and 10.9 kJ mol¯1 for Li, Ni, Mn and Co,respectively. The cathode materials before leaching and the leaching residuewere characterized with different analytical methods. The characterizationresults confirmed that the addition of the waste tea acted as reductant andresulted in better dissolution of the metals, supporting the principles of sustainable processes by decreasing the chemical consumption and integratingwaste into a secondary use.

AB - A hydrometallurgical method involving natural biomass waste as reductantwas proposed for the treatment of spent mixed-type lithium-ion batteries.Results showed that almost complete dissolution of Li, Ni, Mn and nearly 90%dissolution of Co were achieved under the optimal conditions of H2SO4 concentration of 2 M, waste tea biomass dosage of 0.3 g/g, solid/ratio of 50 g L¯1, temperature of 90ºC and time of 120 min. The leaching kinetics was furtherinvestigated, and the activation energies were determined to be 1.7 kJ mol¯1,10.3 kJ mol¯1, 10.1 kJ mol¯1 and 10.9 kJ mol¯1 for Li, Ni, Mn and Co,respectively. The cathode materials before leaching and the leaching residuewere characterized with different analytical methods. The characterizationresults confirmed that the addition of the waste tea acted as reductant andresulted in better dissolution of the metals, supporting the principles of sustainable processes by decreasing the chemical consumption and integratingwaste into a secondary use.

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SN - 1047-4838

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Biomass-Assisted Reductive Leaching in H2SO4 Medium for the Recovery of Valuable Metals from Spent Mixed-Type Lithium-Ion Batteries

Abstract

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