Atomically Sharp 1D Interfaces in 2D Lateral Heterostructures of VSe2─NbSe2 Monolayers

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Abstract

van der Waals heterostructures have emerged as an ideal platform for creating engineered artificial electronic states. While vertical heterostructures have been extensively studied, realizing high-quality lateral heterostructures with atomically sharp interfaces remains a major experimental challenge. Here, we advance a one-pot two-step molecular beam lateral epitaxy approach and successfully synthesize atomically well-defined 1T-VSe2─1H-NbSe2 lateral heterostructures. We demonstrate the formation of defect-free lateral heterostructures and characterize their electronic structure by using scanning tunneling microscopy and spectroscopy together with density functional theory calculations. We find additional electronic states at the 1D interface as well as signatures of Kondo resonances in a side-coupled geometry. Our experiments explored the full potential of lateral heterostructures for realizing exotic electronic states in low-dimensional systems for further studies of artificial designer quantum materials.

Original languageEnglish
Pages (from-to)31300-31308
Number of pages9
JournalACS Nano
Volume18
Issue number45
DOIs
Publication statusPublished - 12 Nov 2024
MoE publication typeA1 Journal article-refereed

Funding

This research made use of the Aalto Nanomicroscopy Center (Aalto NMC) facilities and was supported by the European Research Council (ERC-2017-AdG no. 788185 “Artificial Designer Materials”) and Academy of Finland (Academy professor funding nos. 318995 and 320555, Academy research fellow nos. 338478 and 346654). Computing resources from the Aalto Science-IT project and CSC, Helsinki, are gratefully acknowledged. X.H. thanks Mr. HUANG Ruojun and Mrs. XIONG Dongyan. H.G-H. acknowledges financial support from the Spanish State Research Agency under grant Ramón y Cajal fellowship RYC2021-031050-I.

Keywords

  • DFT
  • lateral heterostructure
  • MBE
  • STM
  • TMDC

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  • ADaM: Artificial designer materials

    Liljeroth, P. (Principal investigator), Shawulienu, K. (Project Member), Alldritt, B. (Project Member), Manninen, I. (Project Member), Gonzalez Herrero, H. (Project Member), Veneranta, L. (Project Member), Silveira Júnior, O. (Project Member), Amini, M. (Project Member), Kipnis, A. (Project Member), Khosravian, M. (Project Member), Aapro, M. (Project Member), Huda, M. N. (Project Member), Otero Fumega, A. (Project Member) & Karjasilta, A. (Project Member)

    01/01/201931/12/2021

    Project: Academy of Finland: Other research funding

  • ADaM: Artificial designer materials

    Liljeroth, P. (Principal investigator), Lemmetty, H. (Project Member), Arslan, B. (Project Member), Karjasilta, A. (Project Member), Gonzalez Herrero, H. (Project Member), Otero Fumega, A. (Project Member), Kipnis, A. (Project Member), Amini, M. (Project Member), Aapro, M. (Project Member), Drost, R. (Project Member) & Khosravian, M. (Project Member)

    01/01/201931/12/2023

    Project: Academy of Finland: Other research funding

  • OtaNano

    Rissanen, A. (Manager)

    Aalto University

    Facility/equipment: Facility

  • OtaNano - Nanomicroscopy Center

    Seitsonen, J. (Manager) & Rissanen, A. (Other)

    OtaNano

    Facility/equipment: Facility

  • Science-IT

    Hakala, M. (Manager)

    School of Science

    Facility/equipment: Facility

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