Abstract
An electrochemical method for the estimation of single ionic salting-out coefficients is presented. The ionic salting-out coefficients of tetrabutyl ammonium and tetraphenyl borate ions were experimentally determined. The scaled particle theory with a simple electrostatic contribution was used to calculate the hard-sphere diameter of these ions. The results were in reasonable agreement with the values obtained by other methods.
| Original language | English |
|---|---|
| Pages (from-to) | 931-936 |
| Number of pages | 6 |
| Journal | Journal of the Chemical Society, Faraday Transactions |
| Volume | 86 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 1990 |
| MoE publication type | A1 Journal article-refereed |
Keywords
- salting-out
- scaled particle theory
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