Abstract
An electrochemical method for the estimation of single ionic salting-out coefficients is presented. The ionic salting-out coefficients of tetrabutyl ammonium and tetraphenyl borate ions were experimentally determined. The scaled particle theory with a simple electrostatic contribution was used to calculate the hard-sphere diameter of these ions. The results were in reasonable agreement with the values obtained by other methods.
Original language | English |
---|---|
Pages (from-to) | 931-936 |
Number of pages | 6 |
Journal | Journal of the Chemical Society, Faraday Transactions |
Volume | 86 |
Issue number | 6 |
DOIs | |
Publication status | Published - 1990 |
MoE publication type | A1 Journal article-refereed |
Keywords
- salting-out
- scaled particle theory