Antimony in flash smelting simulation experiments. Part 1: The behaviour of a high-antimony concentrate (tetrahedrite)

Ari Tapani Jokilaakso*, Risto Olavi Suominen, Pekka Antero Taskinen, Kaj Rainer Lilius

*Corresponding author for this work

    Research output: Contribution to journalArticleScientificpeer-review

    6 Citations (Scopus)

    Abstract

    The removal of sulfur and antimony from a tetrahedritic concentrate containing 25.4% Cu, 21.5% Fe, 20.5% S and 13.8% Sb was studied using a laboratory scale laminar flow furnace. The gas preheating temperatures were 500-1100°C; the atmospheres N2, and N2 with up to 50% O2 and up to 5% SO2. Two narrow particle size fractions were used with x=20-38 μm and x=62-74 μm. Desulfurization was found to proceed continuously along with increasing gas preheating temperature and oxygen concentration. However, a minimum was found in the antimony removal curve. Chemical and morphological analyses of the oxidation products and a thermodynamic approach to the prevailing reaction system were used to determine details of the reaction mechanisms in the flash oxidation of antimony-bearing minerals.

    Original languageEnglish
    Pages (from-to)50-60
    Number of pages11
    JournalScandinavian Journal of Metallurgy
    Volume18
    Issue number2
    Publication statusPublished - 1989
    MoE publication typeA1 Journal article-refereed

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