An Unlockable–Relockable Iron Cage by Subcomponent Self-Assembly

Prasenjit Mal; David Schultz; Ngong Kodiah Beyeh; Kari  Rissanen; Jonathan Nitschke

doi:10.1002/anie.200803066

An Unlockable–Relockable Iron Cage by Subcomponent Self-Assembly

Prasenjit Mal, David Schultz, Ngong Kodiah Beyeh, Kari Rissanen, Jonathan Nitschke

Not published at Aalto University

Research output: Contribution to journal › Article › Scientific › peer-review

271 Citations (Scopus)

Abstract

Linear diamine and formylpyridine subcomponents form a tetrahedral cage with iron(II) in water (see scheme). This cage traps hydrophobic guests with high specificity within a rigid cavity, isolating them from the aqueous environment. The cage may be broken, releasing the guest, upon the addition of a triamine. It may also be unlocked by adding acid, allowing the guest to be reversibly released until base is added, relocking it within.

Original language	English
Pages (from-to)	8297–8301
Journal	Angewandte Chemie (International Edition)
Volume	47
Issue number	43
DOIs	https://doi.org/10.1002/anie.200803066
Publication status	Published - Oct 2008
MoE publication type	A1 Journal article-refereed

Access to Document

10.1002/anie.200803066

SFX availability

Full text

Cite this

@article{9996cf0f610d49f3a172173db7084780,

title = "An Unlockable–Relockable Iron Cage by Subcomponent Self-Assembly",

abstract = "Linear diamine and formylpyridine subcomponents form a tetrahedral cage with iron(II) in water (see scheme). This cage traps hydrophobic guests with high specificity within a rigid cavity, isolating them from the aqueous environment. The cage may be broken, releasing the guest, upon the addition of a triamine. It may also be unlocked by adding acid, allowing the guest to be reversibly released until base is added, relocking it within.",

author = "Prasenjit Mal and David Schultz and Beyeh, {Ngong Kodiah} and Kari Rissanen and Jonathan Nitschke",

year = "2008",

month = oct,

doi = "10.1002/anie.200803066",

language = "English",

volume = "47",

pages = "8297–8301",

journal = "Angewandte Chemie",

issn = "1433-7851",

publisher = "WILEY-VCH VERLAG",

number = "43",

}

TY - JOUR

T1 - An Unlockable–Relockable Iron Cage by Subcomponent Self-Assembly

AU - Mal, Prasenjit

AU - Schultz, David

AU - Beyeh, Ngong Kodiah

AU - Rissanen, Kari

AU - Nitschke, Jonathan

PY - 2008/10

Y1 - 2008/10

N2 - Linear diamine and formylpyridine subcomponents form a tetrahedral cage with iron(II) in water (see scheme). This cage traps hydrophobic guests with high specificity within a rigid cavity, isolating them from the aqueous environment. The cage may be broken, releasing the guest, upon the addition of a triamine. It may also be unlocked by adding acid, allowing the guest to be reversibly released until base is added, relocking it within.

AB - Linear diamine and formylpyridine subcomponents form a tetrahedral cage with iron(II) in water (see scheme). This cage traps hydrophobic guests with high specificity within a rigid cavity, isolating them from the aqueous environment. The cage may be broken, releasing the guest, upon the addition of a triamine. It may also be unlocked by adding acid, allowing the guest to be reversibly released until base is added, relocking it within.

U2 - 10.1002/anie.200803066

DO - 10.1002/anie.200803066

M3 - Article

VL - 47

SP - 8297

EP - 8301

JO - Angewandte Chemie

JF - Angewandte Chemie

SN - 1433-7851

IS - 43

ER -

An Unlockable–Relockable Iron Cage by Subcomponent Self-Assembly

Abstract

Access to Document

SFX availability

Fingerprint

Cite this