An expedient synthesis of D-callipeltose

Ainoliisa J. Pihko, K.C. Nicolaou, Ari M.P. Koskinen

    Research output: Contribution to journalArticleScientificpeer-review

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    Abstract

    Methyl D-callipeltose 12 and D-callipeltose 4 were synthesized from D-glucal 5 in 10 and 11 steps, respectively. The synthesis features an azide displacement reaction of an -nosyloxy ketone 7 and a highly diastereoselective C-methylation of
    alpha-azido ketone 8.
    Original languageEnglish
    Pages (from-to)937-942
    JournalTETRAHEDRON-ASYMMETRY
    Volume12
    DOIs
    Publication statusPublished - 2001
    MoE publication typeA1 Journal article-refereed

    Keywords

    • azides
    • D-callipeltose
    • D-glucal
    • diastereoselective synthesis

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