Advances in upconversion enhanced solar cell performance

Amr Ghazy, Muhammad Safdar, Mika Lastusaari, Hele Savin, Maarit Karppinen*

*Corresponding author for this work

Research output: Contribution to journalReview Articlepeer-review

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Abstract

Photovoltaics (PV) is the leading renewable energy harvesting technology. Thus, there is a remarkable strive to enhance the light harvesting capability of the state-of-the-art solar cells. The major issue common to all solar cell types is that they utilize only a limited portion of the solar spectrum, mostly in the visible range, as the active semiconductor materials suffer from intrinsic light absorption thresholds. As a result, photons below and above these threshold values do not contribute to the electricity generation. A plausible solution to enhance the performance is to integrate the PV cell with an upconverting (UC) component capable of harvesting lower energy photons in the infrared (IR) range and emitting visible light. The concept was first introduced in 1990s, but major progress in the field has been made in particular in the recent few years. In this overview our intention is to provide the readers with a comprehensive account of the progress in the research on the UC-enhanced solar cells. Lanthanide ions embedded in different host lattices constitute the most important UC material family relevant to the PV technology; we first summarize the design principles and fabrication routes of these materials. Then discussed are the different approaches taken to integrate the UC layers in actual PV device configurations. Finally, we will highlight the most prominent results obtained, give some future perspectives and outline the remaining challenges in this scientifically intriguing and application-wise important field.

Original languageEnglish
Article number111234
Number of pages15
JournalSolar Energy Materials and Solar Cells
Volume230
DOIs
Publication statusPublished - 15 Sep 2021
MoE publication typeA2 Review article in a scientific journal

Keywords

  • Atomic layer deposition
  • Lanthanides
  • Luminescence
  • Photonics
  • Solar cells
  • Upconversion

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