Advanced NMR Characterization of Aquasolv Omni (AqSO) Biorefinery Lignins/Lignin-Carbohydrate Complexes

Philipp Schlee, Dmitry Tarasov, Davide Rigo*, Mikhail Balakshin

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

2 Citations (Scopus)
8 Downloads (Pure)

Abstract

Our recently reported AquaSolv Omni (AqSO) process shows great potential as a parameter-controlled type of biorefinery, which allows tuning of structure and properties of the products towards their optimal use in high-value applications. Herein, a comprehensive NMR (quantitative 13C, 31P, and 2D heteronuclear single-quantum coherence) structural characterization of AqSO lignins is reported. The effect of the process severity (P-factor) and liquid-to-solid ratio (L/S) on the structure of the extracted lignins has been investigated and discussed. Low severity (P-factor in the range 400–600) and L/S=1 led to the isolation of less degraded lignin with a higher β-O-4 content up to 34/100 Ar. Harsher processing conditions (P-factor=1000–2500) yielded more condensed lignins with a high degree of condensation up to 66 at P-factor=2000. New types of lignin moieties, such as alkyl-aryl and alkyl-alkyl chemical bonds together with novel furan oxygenated structures have been identified and quantified for the first time. In addition, the formation of lignin carbohydrate complexes bonds has been hypothesized at low severity and L/S. Based on the obtained data we were able to formulate a possible outlook of the occurring reactions during the hydrothermal treatment. Overall, such detailed structural information bridges the gap from process engineering to sustainable product development.

Original languageEnglish
Article numbere202300549
Number of pages12
JournalChemSusChem
Volume16
Issue number18
Early online date23 May 2023
DOIs
Publication statusPublished - 22 Sept 2023
MoE publication typeA1 Journal article-refereed

Keywords

  • integrated biorefinery
  • lignin
  • lignin-carbohydrate complexes
  • NMR spectroscopy
  • reaction mechanisms

Fingerprint

Dive into the research topics of 'Advanced NMR Characterization of Aquasolv Omni (AqSO) Biorefinery Lignins/Lignin-Carbohydrate Complexes'. Together they form a unique fingerprint.

Cite this