A Study of the Composition and Structure of a Solid Electrolyte Interface (SEI) Formed on the Surface of Electrode Material Based on SnOx/Sn@MWCNT Nanocomposite

P. M. Korusenko; S. N. Nesov; V. V. Bolotov; S. N. Povoroznyuk; E. O. Fedorovskaya

doi:10.1134/S2070205121010135

A Study of the Composition and Structure of a Solid Electrolyte Interface (SEI) Formed on the Surface of Electrode Material Based on SnO_x/Sn@MWCNT Nanocomposite

P. M. Korusenko^*, S. N. Nesov, V. V. Bolotov, S. N. Povoroznyuk, E. O. Fedorovskaya

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

1 Citation (Scopus)

Abstract

Abstract: In the process of the performed studies, new information has been obtained about the composition and structure of the solid electrolyte interface (SEI) formed on the surface of electrodes based on the initial composite SnO_x@MWCNT (tin oxide/multiwall carbon nanotubes) and the SnO_x/Sn@MWCNT composite formed by irradiation using a pulsed ion beam of nanosecond duration. It has been shown that, after long сycling of electrode based on an irradiated composite (SnO_x/Sn@MWCNT), the tin concentration remained approximately at the same level. This result indicated high interphase adhesion of the metal–oxide component to the surface of MWCNTs in the irradiated composite. Using X-ray photoelectron spectroscopy methods, it has been established that the SEI layer formed under these conditions consisted predominantly of lithium carbonate and oxide and organic compounds comprising products of interaction of solvents (ethylene carbonate and dimethyl carbonate) of the electrolyte with the electrode surface. It has been found that the electrode based on the irradiated composite demonstrates the best electrochemical characteristics as a material for the electrodes of lithium-ion batteries.

Original language	English
Pages (from-to)	59-67
Number of pages	9
Journal	PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES
Volume	57
Issue number	1
DOIs	https://doi.org/10.1134/S2070205121010135
Publication status	Published - Jan 2021
MoE publication type	A1 Journal article-refereed

Keywords

composites
electrical impedance spectroscopy
electrodes
multiwall carbon nanotubes
NEXAFS)
SnO/Sn nanoparticles with core–shell structure
solid electolyte interface (SEI)
synchrotron radiation
X-ray spectroscopy methods (XPS

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1134/S2070205121010135

OpenUrl availability

Full text

Cite this

Korusenko, P. M., Nesov, S. N., Bolotov, V. V., Povoroznyuk, S. N., & Fedorovskaya, E. O. (2021). A Study of the Composition and Structure of a Solid Electrolyte Interface (SEI) Formed on the Surface of Electrode Material Based on SnO_x/Sn@MWCNT Nanocomposite. PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 57(1), 59-67. https://doi.org/10.1134/S2070205121010135

@article{4e7c0ef7eb03472aa6b24eff67692552,

title = "A Study of the Composition and Structure of a Solid Electrolyte Interface (SEI) Formed on the Surface of Electrode Material Based on SnOx/Sn@MWCNT Nanocomposite",

abstract = "Abstract: In the process of the performed studies, new information has been obtained about the composition and structure of the solid electrolyte interface (SEI) formed on the surface of electrodes based on the initial composite SnOx@MWCNT (tin oxide/multiwall carbon nanotubes) and the SnOx/Sn@MWCNT composite formed by irradiation using a pulsed ion beam of nanosecond duration. It has been shown that, after long сycling of electrode based on an irradiated composite (SnOx/Sn@MWCNT), the tin concentration remained approximately at the same level. This result indicated high interphase adhesion of the metal–oxide component to the surface of MWCNTs in the irradiated composite. Using X-ray photoelectron spectroscopy methods, it has been established that the SEI layer formed under these conditions consisted predominantly of lithium carbonate and oxide and organic compounds comprising products of interaction of solvents (ethylene carbonate and dimethyl carbonate) of the electrolyte with the electrode surface. It has been found that the electrode based on the irradiated composite demonstrates the best electrochemical characteristics as a material for the electrodes of lithium-ion batteries.",

keywords = "composites, electrical impedance spectroscopy, electrodes, multiwall carbon nanotubes, NEXAFS), SnO/Sn nanoparticles with core–shell structure, solid electolyte interface (SEI), synchrotron radiation, X-ray spectroscopy methods (XPS",

author = "Korusenko, {P. M.} and Nesov, {S. N.} and Bolotov, {V. V.} and Povoroznyuk, {S. N.} and Fedorovskaya, {E. O.}",

note = "Funding Information: The authors are grateful to the staff of the Omsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences: to Yu.A. Sten?kin for the synthesis of MWCNT assemblies and to K.E. Ivlev for the formation of composites by the CVD method, as well as to A.I. Pushkarev, a staff member of Tomsk Polytechnic University, for irradiation of the composite samples by a PIB. The authors also grateful to management of the Omsk Regional Shared Equipment Center SB RAS for providing equipment for sample analysis by the SEM and EDX methods and to the administration of the Russian-German channel of the BESSY II synchrotron storage for assistance in conducting studies by the XPS and NEXAFS methods. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = jan,

doi = "10.1134/S2070205121010135",

language = "English",

volume = "57",

pages = "59--67",

journal = "PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES",

issn = "2070-2051",

publisher = "MAIK Nauka/Interperiodica",

number = "1",

}

A Study of the Composition and Structure of a Solid Electrolyte Interface (SEI) Formed on the Surface of Electrode Material Based on SnO_x/Sn@MWCNT Nanocomposite. / Korusenko, P. M.; Nesov, S. N.; Bolotov, V. V. et al.
In: PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, Vol. 57, No. 1, 01.2021, p. 59-67.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - A Study of the Composition and Structure of a Solid Electrolyte Interface (SEI) Formed on the Surface of Electrode Material Based on SnOx/Sn@MWCNT Nanocomposite

AU - Korusenko, P. M.

AU - Nesov, S. N.

AU - Bolotov, V. V.

AU - Povoroznyuk, S. N.

AU - Fedorovskaya, E. O.

N1 - Funding Information: The authors are grateful to the staff of the Omsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences: to Yu.A. Sten?kin for the synthesis of MWCNT assemblies and to K.E. Ivlev for the formation of composites by the CVD method, as well as to A.I. Pushkarev, a staff member of Tomsk Polytechnic University, for irradiation of the composite samples by a PIB. The authors also grateful to management of the Omsk Regional Shared Equipment Center SB RAS for providing equipment for sample analysis by the SEM and EDX methods and to the administration of the Russian-German channel of the BESSY II synchrotron storage for assistance in conducting studies by the XPS and NEXAFS methods. Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1

Y1 - 2021/1

N2 - Abstract: In the process of the performed studies, new information has been obtained about the composition and structure of the solid electrolyte interface (SEI) formed on the surface of electrodes based on the initial composite SnOx@MWCNT (tin oxide/multiwall carbon nanotubes) and the SnOx/Sn@MWCNT composite formed by irradiation using a pulsed ion beam of nanosecond duration. It has been shown that, after long сycling of electrode based on an irradiated composite (SnOx/Sn@MWCNT), the tin concentration remained approximately at the same level. This result indicated high interphase adhesion of the metal–oxide component to the surface of MWCNTs in the irradiated composite. Using X-ray photoelectron spectroscopy methods, it has been established that the SEI layer formed under these conditions consisted predominantly of lithium carbonate and oxide and organic compounds comprising products of interaction of solvents (ethylene carbonate and dimethyl carbonate) of the electrolyte with the electrode surface. It has been found that the electrode based on the irradiated composite demonstrates the best electrochemical characteristics as a material for the electrodes of lithium-ion batteries.

AB - Abstract: In the process of the performed studies, new information has been obtained about the composition and structure of the solid electrolyte interface (SEI) formed on the surface of electrodes based on the initial composite SnOx@MWCNT (tin oxide/multiwall carbon nanotubes) and the SnOx/Sn@MWCNT composite formed by irradiation using a pulsed ion beam of nanosecond duration. It has been shown that, after long сycling of electrode based on an irradiated composite (SnOx/Sn@MWCNT), the tin concentration remained approximately at the same level. This result indicated high interphase adhesion of the metal–oxide component to the surface of MWCNTs in the irradiated composite. Using X-ray photoelectron spectroscopy methods, it has been established that the SEI layer formed under these conditions consisted predominantly of lithium carbonate and oxide and organic compounds comprising products of interaction of solvents (ethylene carbonate and dimethyl carbonate) of the electrolyte with the electrode surface. It has been found that the electrode based on the irradiated composite demonstrates the best electrochemical characteristics as a material for the electrodes of lithium-ion batteries.

KW - composites

KW - electrical impedance spectroscopy

KW - electrodes

KW - multiwall carbon nanotubes

KW - NEXAFS)

KW - SnO/Sn nanoparticles with core–shell structure

KW - solid electolyte interface (SEI)

KW - synchrotron radiation

KW - X-ray spectroscopy methods (XPS

UR - http://www.scopus.com/inward/record.url?scp=85102367510&partnerID=8YFLogxK

U2 - 10.1134/S2070205121010135

DO - 10.1134/S2070205121010135

M3 - Article

AN - SCOPUS:85102367510

SN - 2070-2051

VL - 57

SP - 59

EP - 67

JO - PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES

JF - PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES

IS - 1

ER -