A straightforward approach towards glycoamino acids and glycopeptidesviaPd-catalysed allylic alkylation

Jan Deska, Uli Kazmaier, Katja Krämer, Christina Hebach

Research output: Contribution to journalArticleScientificpeer-review

Abstract

Chelated enolates are versatile nucleophiles for palladium-catalysed allylic alkylations. Even with complex allylic substrates the reaction proceed without significant isomerisation. This allows the stereoselective introduction of polyhydroxylated allylic sidechains into amino acids and peptides with retention of the olefin geometry.
Original languageEnglish
Pages (from-to)103-110
Number of pages8
JournalORGANIC AND BIOMOLECULAR CHEMISTRY
Volume7
DOIs
Publication statusPublished - 24 Sep 2008
MoE publication typeA1 Journal article-refereed

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