A hierarchical Ca/TiO2/NH2-MIL-125 nanocomposite photocatalyst for solar visible light induced photodegradation of organic dye pollutants in water

Najmeh Ahmadpour, Mohammad Hossein Sayadi*, Shahin Homaeigohar

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

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Abstract

In this study, for the first time, the Ca/TiO2/NH2-MIL-125 nanocomposite photocatalyst was synthesized for the purpose of photodegradation of Methyl Orange (MO) and Rhodamine B (RhB) dyes under visible light irradiation. The structural and chemical properties of the nanocomposite photocatalyst were characterized through FTIR, XRD, TGA, PL, XPS, ICP-OES and UV-DRS. For the photodegradation efficiency analysis, the effect of pH (3, 5, 7, 9, and 11), photocatalyst dosage (0.1, 0.2, 0.4, 0.6, and 0.8 g L-1), dye concentration (1-40 mg L-1), and contact time (10-120 min) was precisely evaluated. The largest photodegradation efficiency for RhB and MO dye models was 82.87% and 86.22%, respectively, that was obtained under optimal conditions in terms of pH and photocatalyst dosage and for Ca(30%)/TiO2/NH2-MIL-125. The photodegradation process of the dyes complied well with the first-order kinetic model. Moreover, the nanocomposite photocatalyst showed consistent photodegradation efficiency and after 6 successive cycles with fresh dye solutions, it could still perform comparably well. Taken together, Ca/TiO2/NH2-MIL-125 photocatalyst is able to show a high photodegradation efficiency for dye pollutants and optimum stability and reusability.

Original languageEnglish
Pages (from-to)29808-29820
Number of pages13
JournalRSC Advances
Volume10
Issue number50
DOIs
Publication statusPublished - 16 Aug 2020
MoE publication typeA1 Journal article-refereed

Keywords

  • HIGHLY-EFFICIENT
  • SELECTIVE OXIDATION
  • METHYL-ORANGE
  • DEGRADATION
  • FRAMEWORK
  • GRAPHENE
  • POLYMER
  • CA
  • NANOPARTICLES
  • AZITHROMYCIN

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