A 1D Coordination Polymer of UF5 with HCN as a Ligand

Benjamin Scheibe, Stefan S. Rudel, Magnus R. Buchner, Antti J. Karttunen, Florian Kraus*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

6 Citations (Scopus)
26 Downloads (Pure)

Abstract

β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.

Original languageEnglish
Pages (from-to)291-295
Number of pages5
JournalCHEMISTRY: A EUROPEAN JOURNAL
Volume23
Issue number2
DOIs
Publication statusPublished - 5 Jan 2017
MoE publication typeA1 Journal article-refereed

Keywords

  • coordination polymer
  • cyanides
  • fluorides
  • uranium
  • X-ray diffraction

Fingerprint Dive into the research topics of 'A 1D Coordination Polymer of UF<sub>5</sub> with HCN as a Ligand'. Together they form a unique fingerprint.

  • Cite this