A 1D Coordination Polymer of UF5 with HCN as a Ligand

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A 1D Coordination Polymer of UF5 with HCN as a Ligand. / Scheibe, Benjamin; Rudel, Stefan S.; Buchner, Magnus R.; Karttunen, Antti J.; Kraus, Florian.

In: CHEMISTRY: A EUROPEAN JOURNAL, Vol. 23, No. 2, 05.01.2017, p. 291-295.

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Scheibe, Benjamin ; Rudel, Stefan S. ; Buchner, Magnus R. ; Karttunen, Antti J. ; Kraus, Florian. / A 1D Coordination Polymer of UF5 with HCN as a Ligand. In: CHEMISTRY: A EUROPEAN JOURNAL. 2017 ; Vol. 23, No. 2. pp. 291-295.

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@article{18ca4a6d58994eb2ab3d588ab90141e5,
title = "A 1D Coordination Polymer of UF5 with HCN as a Ligand",
abstract = "β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.",
keywords = "coordination polymer, cyanides, fluorides, uranium, X-ray diffraction",
author = "Benjamin Scheibe and Rudel, {Stefan S.} and Buchner, {Magnus R.} and Karttunen, {Antti J.} and Florian Kraus",
year = "2017",
month = "1",
day = "5",
doi = "10.1002/chem.201605293",
language = "English",
volume = "23",
pages = "291--295",
journal = "CHEMISTRY: A EUROPEAN JOURNAL",
issn = "0947-6539",
number = "2",

}

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TY - JOUR

T1 - A 1D Coordination Polymer of UF5 with HCN as a Ligand

AU - Scheibe, Benjamin

AU - Rudel, Stefan S.

AU - Buchner, Magnus R.

AU - Karttunen, Antti J.

AU - Kraus, Florian

PY - 2017/1/5

Y1 - 2017/1/5

N2 - β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.

AB - β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.

KW - coordination polymer

KW - cyanides

KW - fluorides

KW - uranium

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85009180560&partnerID=8YFLogxK

U2 - 10.1002/chem.201605293

DO - 10.1002/chem.201605293

M3 - Article

VL - 23

SP - 291

EP - 295

JO - CHEMISTRY: A EUROPEAN JOURNAL

JF - CHEMISTRY: A EUROPEAN JOURNAL

SN - 0947-6539

IS - 2

ER -

ID: 10573508