A 1D Coordination Polymer of UF5 with HCN as a Ligand

Research output: Contribution to journalArticleScientificpeer-review

Researchers

  • Benjamin Scheibe
  • Stefan S. Rudel
  • Magnus R. Buchner
  • Antti Karttunen

  • Florian Kraus

Research units

  • University of Marburg

Abstract

β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.

Details

Original languageEnglish
Pages (from-to)291-295
Number of pages5
JournalCHEMISTRY: A EUROPEAN JOURNAL
Volume23
Issue number2
Publication statusPublished - 5 Jan 2017
MoE publication typeA1 Journal article-refereed

    Research areas

  • coordination polymer, cyanides, fluorides, uranium, X-ray diffraction

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