Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]2 2- with a cavity volume of 165 3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50:50 ratio in the crystal lattice.
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Beyeh, N. (Creator), Kalenius, E. (Creator), Puttreddy, R. (Creator) & Rissanen, K. (Creator), Cambridge Crystallographic Data Centre , 1 Jan 2017
Beyeh, N. (Creator), Kalenius, E. (Contributor), Puttreddy, R. (Contributor) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 Jan 2017